Spectroscopy and Photochemical Dynamics of the CF3S Radical
نویسندگان
چکیده
The CF3S radical has been investigated using the LIF and fluorescence depletion techniques. The vibrational structure of the first excited à A1 state has been assigned. The photodissociation process at energies above the origin of the à state has been characterized by fluorescence temporal decay and fluorescence depletion spectroscopy. Above the photodissociation threshold the ratio of the rates for the competing processes of emission and dissociation varies strongly with both energy and vibrational mode.
منابع مشابه
Laser Induced Fluoresence and Fluoresence Depletion Spectroscopy of the Jet-Cooled CF3S Radical
David E. Powers, Michael Pushkarsky and Terry A. Miller Laser Spectroscopy Facility The Ohio State University 120 W. 18th Avenue Columbus OH 43210 The spectrum of the CF3S free radical has been observed for the first time cooled in a supersonic free jet expansion. Both ”bright” and ”dark” levels of the à state have been observed using a combination of laser induced fluoresence and fluoresence d...
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